100th anniversary for Type-B nickel-base (Ni-Mo) alloys

The B-type alloys have been used mainly in hydrochloric and sulfuric acid environments, as well as in acetic, phosphoric, and formic acids. Specific applications include reaction vessels, heat exchangers, valves, pumps, and piping.
The B-type alloys have been used mainly in hydrochloric and sulfuric acid environments, as well as in acetic, phosphoric, and formic acids. Specific applications include reaction vessels, heat exchangers, valves, pumps, and piping.

Prior to the introduction of the workhorse C-family of nickel-base alloys (Ni-Cr-Mo) in the early 1930s, work had been conducted on nickel-molybdenum alloy compositions. This resulted in the award of a patent, in 1921, for a nickel-molybdenum alloy composition range, which ultimately led to the introduction of Alloy B (Ni-Mo) in 1923 with a nickel content of 60% and nearly 30% molybdenum.

By Geir Moe, Nickel Institute

B-type alloys possess exceptional resistance to reducing acids, such as hydrochloric, sulphuric, acetic, and phosphoric. Unfortunately, B-type alloys have poor corrosion resistance to oxidising environments. Hence, they are not recommended for use in oxidising media or in the presence of ferric or cupric salts which may cause rapid premature corrosion failure. These salts may develop when hydrochloric acid comes in contact with iron and copper. Prior to the Second World War, Alloy B was used in supercharger turbine blades in aircraft engines to boost performance and increase horsepower. This application was eventually replaced by other superalloys.

Alloy (UNS) Introduction Ni Mo Cr SI max Fe C max
B (N10001) 1923 bal 28 1 1 5 0.05
B-2 (N10665) 1970s bal 28 1 0.10 2 0.02
B-3 (N10675) 1990s bal 28 2 0.10 2 0.01

Typical composition of the B-family alloys.

Alloy B-2, introduced in the 1970s, was a modification of the original B composition.
It featured reduced silicon and carbon content, to improve thermal stability and resist the formation of grain boundary carbides. This improvement in corrosion resistance was particularly beneficial in the heat-affected zone after welding. The composition was additionally optimised in Type B-3 to further enhance thermal stability and fabrication characteristics and resistance to stress corrosion cracking.
Molybdenum primarily provides the corrosion resistance to acidic reducing environments, but it is the nickel-base that provides the foundation for an engineering alloy that can be easily fabricated and welded into industrially useful equipment.

About Nickel Institute

The Nickel Institute is the global association of leading primary nickel producers. Its mission is to advocate for the responsible supply and sustainable development of nickel and the nickel industry. For information, visit nickelinstitute.org/

About this Tech Article

This tech article appeared in Stainless Steel World, December 2023 magazine. To read many more articles like these on an (almost) monthly basis, subscribe to our magazine (available in print and digital format) – SUBSCRIPTIONS TO OUR DIGITAL VERSION ARE NOW FREE.

Every week we share a new Featured Story with our Stainless Steel community. Join us and let’s share your Featured Story on Stainless Steel World online and in print.

Previous articleAcerinox to acquire Haynes International
Next articleStainless steel welding characteristics & suitability with dissimilar metals
Stainless Steel World is part of The KCI Media Group, a group of companies focused on building and sustaining global communities in the flow control industries. We publish news on a daily basis and connect business-to-business professionals through our online communities, publications, conferences and exhibitions.